Later you have a family and responsibility for your children. In college you are free and can take risks.
Even if you do think that having a child will slow you down, being older doesn't automatically mean you will become a parent... the technology in that field is pretty good at this point.
Starting a business before 20-21 is not really ideal. Yes, some people can do it. But those people have an over the top mental and emotional maturity that nominal case is lacking, and college is a great way to get there.
Are you really suggesting that you see a CEO in a nominal high school graduate? Most of them don't have a slightest clue how to deal with people, let alone negotiate their terms -- knowledge in domain being aside.