For building a long-standing product or business, I would argue that Pinterest, AirBnB, 23andMe, GMail, and Yahoo Mail all qualify, as does YC itself. That's why they haven't exited: Ben/Joe/Anne are all still building their businesses.
For exiting: PG/TLB/RTM (Viaweb), Kevin Hale (Wufoo), Justin Kan (Twitch), Michael Siebel (SocialCam), Paul Buchheit (FriendFeed) and Alexis Ohanian (Reddit) all exited for F-U amounts of money. Sam Altman (Loopt), Dalton Caldwell (iMeem), Garry Tan (Posterous), Qasar Younis (Talkbin), and Geoff Ralston (Lala) may have, but it's unclear from public documents whether the acquisitions of their companies resulted in a significant payoff to them after the liquidation preferences of their investors are taken into account.