What you are about to do is to layer one IPSP on top of another so you control the stream of funds. Because you outsource the bulk of the problems to the IPSP below you you will have a relatively easy time of it.
If your merchants are going to use your platform (it is hard to say exactly what you will run in to without knowing a whole lot more about your project, but I understand you do not want to put all your cards on the table) then you will want to keep the balance you hold for them as low as possible to reduce the risk in case something goes wrong.
I'm actually working on a very long post (more like a small book) regarding the whole internet payment process, likely it will too much time for you to wait until it is done.
Ideally you would make a deal with an IPSP to see you as an affiliate, and get every merchant their own account with the IPSP. That way your exposure is limited and in case of conflict it will be between the merchants and the IPSP you pick.
Some, but not all IPSPs support this kind of functionality, the 'split' is usually either a fixed amount per transaction or a %age of the total sales volume.
You will have to figure in a two to six week 'holdback' period which is used to create a reserve in case of massive chargebacks due to fraud, it is also a major source of income for IPSPs and a major source of trouble in case one goes under.