https://www.mela.fi/sites/default/files/lietelanta.pdf
"Description of event
A farm-owner suffocated inside a manure tank which was lacking oxygen and contained toxic gases. Also his brother, who went in to help, died.
A tank of liquid-form manure was almost empty. A pipe at the bottom of the tank was blocked. The farm owner decided to enter the tank and finalize emptying the tank. However, he lost consciousness and fell to the bottom.
His brother, who was close by, saw what happened and went in to save the unconscious man, but he was also overcome in a moment. Four hours later a family member discovered the victims. Fire service was called to help, and with pressure air breathing equipment, they retrieved both men. They were both found to be dead. Cause of death was a poisoning by methane and hydrogen sulfide."
(Taken from farm advisory leaflet on manure https://www.mela.fi/sites/default/files/lietelanta.pdf )