1) Sign up for intercom.io. It's genuinely the best customer support tool I've used.
2) Get the app and get a notification for every user's question. Try to answer them the second you see it.
3) Don't hire a dedicated customer support person. Stay close to your customers and build a relationship.
4) Watch this talk by Patrick Collison from Stripe: https://www.youtube.com/watch?v=nnllRegL_NI
5) Build out an FAQ
6) Make sure your customers are happy.