Eh. I got my undergrad at a second-tier university and my MSc at a top-tier one. There's definitely been a perceptible difference in how people treat me.
It's another form of social proof, and it affects not just whether or not you get hired, but how people view you, speak to you, and whether / how much they listen to or consider your opinion. Of course, many people don't give degrees a second thought, but for every one of those, there are plenty who do.
I am saying I would rather employee someone who had worked for a year in my field than someone who had done a Masters straight after their Bachelors.