In the Indian subcontinent, certain clay's have been used since ages to help with wound healing and as an antiseptic.
Also "moldy bread was used in China, Greece, Serbia, Egypt and probably other ancient civilizations as treatment for some disease conditions, particularly infected wounds. The observed curative powers may have been due to some raw forms of antibiotics produced by the mold growing on the bread".
http://amrls.cvm.msu.edu/pharmacology/historical-perspective...