[0] http://www.telegraph.co.uk/news/health/news/11981884/Cooking...
[0] http://www.telegraph.co.uk/news/health/news/11981884/Cooking...
This is because poly- and mono-unsaturated fats had double bonds that oxidize rapidly. A free radical colliding with one of those double bonds will set off a chain reaction, resulting in rancidity.
In comparison, saturated fats have single bonds that do not oxidize as rapidly after a free radical challenge.
The processing step that the fake oils use will degrade the antioxidant capacity that you'd get from real, cold-pressed oil.
So, in summary:
PUFA's go rancid easily in absence of antioxidants.
Pure EVOO, though PUFA, has antioxidants that protect it.
If you buy "EVOO" in the US, it has possibly undergone processing (despite the label!), which means that it will have lower antioxidative capacity
Wiki article: