[EDIT] Also want to add that people grossly underestimate the responsibility of being their own boss. There are a lot of tasks you have to handle outside of your usual work like finances, scheduling, client outreach, etc...
The OP seemed to understand this, but a lot of people will create a start-up for the sake of being on the creating end of something without really knowing how practical their venture really is.
Paul Grahm may disagree though.