If you mean Linden would have issues with chargebacks for people exchanging real money -- why wouldn't any BTC exchange have the same problem? It seems unlikely you'll be able to buy $0.01 of BTC.
In fact, any centralize system that throws out chargebacks should have zero problems scaling. A few years ago VISA said their target was around 50K tx/sec peak (though their daily peak is only a few thousand). It'd be slightly odd for a centralized system to not be able to easily scale to that volume.
Forgive me if I'm misunderstanding the thread.