This is because of the "stake" people are seeking when looking for a marriage between genders. Women are seeking wealth, social status, personality and whatever it may take to maintain a stable marriage ( family). While men, in most cases, are looking for prettiness, good-looking or whatever superficial. This kind of value lifespan and marriage purpose mismatch is the whole problem of marriage issues in China.
A divorced, less pretty (compare to those in 20s), mid-aged woman is very hard to find another marriage. Even if they did not even marry before, it is still hard for them. A lot of women in China who are well-educated, well-paid, in their 30s still have problems in finding partners (This is what Chinese society called sheng nu, or "women that left behind":https://en.wikipedia.org/wiki/Sheng_nu).
Statistically speaking, women are indeed more than men, but the mating process is not statistic.