In those cases, I would rather have XML config files than undocumented binary blobs as config files. When I see an XML config file, I feel a little relief that it's not a binary blob rather than disappointment that it's not freeform text, because I assume that freeform text must've been off the table for whatever reason (which, depending on what the config file is for, can be a totally rational and reasonable thing to do).
I don't work in specialties where XML has a ton of visibility though- maybe there are lots of projects out there that I don't use in which people are required to hand-edit XML config files, as opposed to "it's in XML, so you could edit it directly, but really no one should be modifying the file with a text editor unless the preferred indirect mechanism isn't an option in some specific case".