While currently it doesn't really add anything from a security perspective the ability to run rendering in a separate process will allow it to very naturally support a number of operating system mitigations that it otherwise would not have in addition to adding restrictions on the process itself (sandboxing).
I believe this will allow Firefox to start to adapt to a more defense in depth philosophy although I admit it's probably still a long way to actually getting there. There's no getting around the fact that security in Firefox has been rather stale but e10s gives something to look forward too since the multi-process architecture allows you to do so much more for defense in depth.