Would you suggest the Nix Pills series now? I notice it's 2 years old.
That said, note that it starts to be relevant when you're starting to write Nix expressions (meaning, write something in Nix language). Sometimes also when you want to read them and understand them. Which... is probably quite soon after starting to use Nix/NixOS, if you'll want to tweak some configs or add custom new packages. If you're really, really just doing first steps with Nix/NixOS, and/or just use the default packages with only simple tweaks, I'd say you don't need to read it yet (I personally wouldn't grasp enough basics then to understand WTF the articles are talking about at that point).