As an additional, somewhat controversial comment, I think these tools are important because there's quite a bit of corruption with publishing. In short, if you're well known and liked author, you often get a pass on your papers and they're not well checked for errors. I've been yelled at by editors for questioning proofs of famous people. I'm not the only one. No. I will not name names or publications. Also, although it's not universal, when some journals say communicated by so-and-so, that means that so-and-so vouched for the paper, so they published it immediately without other peer review. Is the paper right? Maybe. However, I find the practice unsettling.
Bringing the comment back to proof assistant tools, I believe they would remedy some, but not all of the problems described above. We don't have to worry if a paper got a pass because the author was well liked. When can just run the proof through the tool and check that it's correct.
Anyway, if someone has some references or tutorials for people using proof assistant tools for applied math kinds of results, I'd love to read them. Things like stability regions for ODE solvers or convergence results for stuff like Newton's method. Or, honestly, anything that helps understand the tools and methodology more easily.