Sooner or later key-derivation schemes gets outdated and requires a better version as happened to bcrypt [1] and will happen to scrypt [2].
It is not "whatever OpenSSL provides" but just combining strong algorithms over to spread the "getting outdated" risks. Think like you are investing your money? Would you prefer betting on just one thing or spreading it over various different investment opportunities?
[1] http://www.unlimitednovelty.com/2012/03/dont-use-bcrypt.html [2] http://blog.ircmaxell.com/2014/03/why-i-dont-recommend-scryp...