Splitting CO2 will always require more energy than was released in making it. Where does that energy come from? They say solar panels. Because of course they do. But why would you burn fossil fuels to make energy, then use solar panels to turn CO2 into batteries? Why not just use solar panels in the first place? It would be far more efficient.
Also, we put about 10 Gigatons of CO2 into the atmosphere each year. 2.7Gt of that is carbon. Just how many batteries are you planning on making from that? Does each person on Earth need half a ton of batteries?
Who's absorbing the astronomical costs of making batteries with atmospheric CO2, rather than with any of the sane carbon sources just lying around?
This plan is nonsensical. It's like solar roadways. It's stupidly expensive, and it just won't work. It's another bogus project dreamed up to make use of green tech research grants that will never see the light of day.