Google image search for monocrystalline solar cell and you'll see they are all square. I had a brief go at searching for anything to back up my claim but lost interest.
I might simply be that the silicon ingot they are cut from is cast round, see this[1] picture and it's less wasteful to cut a square with chamfered corners than to cut a rectangle, which would necessitate an ingot with an elliptical cross section, which would probably be harder to cast due to uneven cooling, maybe.
1. http://www.tindosolar.com.au/learn-more/poly-vs-mono-crystal...
I found this[1] video that explains how to grow a monocrystalline silicon ingot that weighs 440 pounds, and you're right it is spun as it's extracted from molten silicon.