I am not quite sure what you mean. There is tons of experimental evidence for quantum mechanics.
Specifically for electron spin, you seem to agree that it has spin 1/2 (because you say that it can be spin up or spin down). But that already concedes that there are superpositions of up and down. Spin left, spin right, spin straight forward, spin backward are all equal superpositions of spin up and spin down; and all these states are trivially constructed.