Why was that? Does the low pressure force oxygen out of the blood in the lungs and thereby having oxygen "free" blood arriving in the brain? If you hold your breath you can easily hold it for a minute without loosing consciousness. So the low pressure must be actively taking oxygen out of the blood, otherwise I can't see that you would loose consciousness in 15 seconds.
How long did it take for Dave Bowman to exit the pod and pressurize the airlock? :)