1. Once it's up and people actually use it, I have to be much more careful about uptime, monitoring, and changing how data is stored. This is by far the scariest thing.
2. Handling a large temporary spike in load when I publish the URL here or elsewhere
3. How -- if I actually knew what I wanted to charge for -- to integrate payment into the application, and what I'm supposed to do tax-wise with the money I'd get.