I only know JavaScript (and I know it quite well). Why learn a whole other language, when Node gets the job done just fine?
Especially one with different paradigms
Web development is about many things. HTML, CSS, performance, accessibility, security, networking, supporting different browsers, polyfills and workarounds, keeping up with new features, UX and usability. Then there are frameworks and build tools, which are all of course JavaScript-based.
Only a small part of web development is actual programming, and the fact that frameworks most of the time lay out the patterns for you, makes the “programmming” aspect even less significant in the overall picture.
So no, I don’t think that learning another programming language is a good way to spend your time if you’re a web developer.