There's more about it in this old usenet thread: https://groups.google.com/forum/#!topic/alt.folklore.compute...
Mass-storage back then was often done with tape decks, which were a lot cheaper than hard disks, and the triple-sync trick was a common firmware trick that tape-drive vendors used to get a cheap 'rewind command' out there for their users, without requiring platform-specific bins for the job.
And if I recall, this was a built-in of the tape-drive itself, which could be used on multiple different systems, and so the triple-sync being used to rewind wasn't Risc/OS specific; I remember using the same tape-deck later on Linux and Irix machines, same ol' sync command worked every time.
I can still hear the whirr in my mind ..