This is a good set of tutorials to get you started : http://www.noupe.com/tutorial/the-ultimate-collection-of-bri...
Also the only corporate looking tutorial "Design a Professional Business Web Layout Use drop-shadows and gradients to create a stylish 3-D look." (about a third of the way down) looks terrible! Unbalanced, unfinished and instead of professional just looks deliberately boring and stereotyped.
Having said all that, they are a nice set of tutorials, thanks!