The value of PoW in cryptocurrency is that I know for a fact that you have to burn $X million dollars if you want to double-spend my cryptocurrency. That has to be burned in electricity, and that burn can't be used for anything else. It's expensive for you to attack me.
If suddenly we've got useful works, such that you can apply that $X million in electricity to solve problems that are actually not wasteful, and worth perhaps $X million dollars in solutions, then I don't actually have confidence that it costs you money to double-spend my transaction. You might be able to double-spend my transaction as a by-product of computation that you were going to do already.
Further, useful PoW is a centralizing pressure, because not everyone is going to have equal access to people who are willing to pay for solutions of useful work. This unequal access to revenue means unequal ability to compete, favoring people who are able to sell solutions more effectively. For cryptocurrency, we like to remove these advantages as much as possible (granted, the existing system has a lot of room for improvement, but useful work moves things in the wrong direction).