Without distribution a key/value store is a hash table. To have any value added it's going to need to be a distributed key/value store. Distributed key/value stores, however, run just as well on commodity hardware. Problem is very few companies work at a scale at which per machine efficiency, power or other cost savings are going to matter; that's a very small market and one that's difficult to sell to.
On the other hand, a customized Linux distribution with a nice UI for deploying key/value stores would be a good idea.