H3 mining is another thought.
Edit: other ideas
* Autonomous vehicles sent ahead of time to build habitats for people.
* Large underground bases dug into the bedrock positioned at the poles collecting solar energy.
* Long tracks to launch things into space/earth electromagnetically.
* Mining of ice which could get split into H and O for propellant.
* Mining of other materials to be used on site or sent back to earth.
* Attempt to get people to be self sufficient on another world, even if it took a hundred years.
* Depot for deep space asteroid mining ships/drones to drop off their cargo and refuel/repair without having to drop all the way down to Earth.