I think more than likely the talking about a certain subject makes the ads stand out more than they would have. It's like, researching to buy a new car, all of a sudden you see that car everywhere on the road. It was there before but you just didn't notice it.
That's my take on it. Again, it's not be impossible. I just think it would be highly likely for facebook of all companies to directly snoop. (Maybe by proxy of other apps?) </TinFoilHat>