No it doesn't. It makes her a good bet to go get another masters or PHD, but being an entrepreneur is a completely different skill set. While her accomplishments are grand in their own right, they're also rather focused.

There's nothing in and of itself on the resume that shows that she's had to work to overcome a default, or has experience building a company, or that she can think on her feet, for example. Although she may in fact possess these skills, I wouldn't take them as a given simply because she has a lot of book smarts.