People are strange. I can totally picture someone who is an experienced senior, a hero under the pressure of a critical production outage, yet whose brain goes into a crash loop when sitting across from someone who has the power to deny them their dream job.
Not claiming to be that hero, but I have personally had those moments where I came out of the interview, and as the disorienting fog of pressure lifted during my drive home I said to myself, "WTF happened to my brain in there? I know that stuff cold!"
EDIT: I think I read this one from a commenter here, but it's so true: We're interviewing people to be music composers, but judging them by their ability to be performance artists.