Step two: Obtain a certificate from Let's Encrypt using website validation.
Step three: Proxy traffic through a proxy you provide that SSL cert for and capture anything you like. In the event that a website legitimately has a higher-class Extended Validation cert or other such thing, hope users don't notice the downgrade from Extended Validation correct SSL cert to a merely correct SSL cert, which is a pretty solid hope.
Certs don't have any sort of overriding or superseding property. A given cert and its chain of signatures is either accepted because you trust the signers, or it isn't; at the time you are making that decision, you don't have access to know whether any other certs have been issued since then or anything.
One thing that comes to mind is that browsers really ought to scream if they see a domain that was previously Extendedly Verified drop down to a Let's Encrypt-level cert. Though how much good this would do in practice is hard to tell... "Hmmm, what's this about the SSL cert being less good? It still has one, right? Let's just click through this... hmm... looks like the web site I expected... must just be the computer being weird enters password"
For example, if you have a service running on multiple backed servers, you might want to have once certificate per server for all of your domains.