These keys are usually stored on a HSM. Even if you want to, you wouldn't be able to access the keys stored inside. This is specifically designed to protect against rogue/bribed personnel.
So it's highly unlikely that the stuxnet developers had possession of the key. I'd bet that they somehow had access to the HSM, to have it sign the driver for them.
Companies of this size are audited regularly, so access to the HSM is expected to be strictly controlled.
So yes, it is a pretty secure location, and a highly guarded secret. The fact that they pulled it of to break into not one, but two of those secrets is extremely impressive on it's own.