I've seen it a hundred times: decisions (or at least discussions) driven by accidental meetings on planes or trains. Something overheard at the pool or in a bar.
It's because these guys know at some level that they're in a closed chamber, away from the reality that underlies their corporate activity and if they think they've suddenly been given an authentic glimpse of something, unmediated by their lieutenants then they find that extremely novel and exciting.
They're just human beings. Often they're very interested in people in general.