I'd argue you can't.
Right now I'm working on a feature that I estimated as 'a couple of hours'. I've been working on it all day by now. Not because the feature is that difficult, or because I didn't get a set of good requirements. The requirements are crystal clear and should be easy to implement.
The reason it's taking so long is that I'm fighting with a UI component that doesn't behave as expected (or documented). What should have been a trivial part of this task, a matter of seconds and not worth estimating at all, turns out to take all day because I didn't know this specific component is misbehaving and I couldn't have known until I started implementing it.
You cannot predict things like that without doing it.