* If your internal workflow is designing documents then the conversion to a web document will be clunky at best.
* Every end-user device has a PDF reader and their web browser probably opens it transparently.
* You need the PDF either way way because the website will never be the authoritative source so now you have the problem of making sure they don't get out of sync.
* You probably have a few internal graphic designers that can do wonders with print but it's unlikely you have an internal web development team.
* It's much easier to make a PDF accessible than a website. (Before you disagree remember that the offices we're talking about likely don't have a dedicated web designer) You can be sure it will print correctly, and for most users it's automatically offline.