I've been thoroughly impressed watching web.go come together. It's now the top Go project on Github in every category they track: http://github.com/languages/Go
Personally I'm of the opinion that language expressiveness matters more than real world performance, but only to a limit. Go is definitely carving out a nice niche for performant systems-related apps.
And the fact that Smart Twitter serves 90k concurrent users from a VPS without breaking a sweat is freaking amazing. I suspect this is the reason the service can remain free.
(edit: err, for the "watched" categories)