This is why I would not worry about pip freeze being non-reproducible. It is a manual step: upgrade our dependencies. Testing should happen all the time. If you are happy with the result of testing after upgrading dependencies, commit requirements.txt. I don't see new tools easing the burden of co-ordinating and testing dependency upgrades. Did I misunderstand them in this context?
I don't understand the concern for the library case. Pipenv doesn't address libraries. It seems to be an explicit goal of many people not to pin library dependencies. I'm asking what the new tools are solving - and again I can't see that they are solving this. Nothing is preventing you from pinning your library dependencies if you want (using old tools) but you'll probably get people complaining about being incompatible with other projects.