https://www.theverge.com/2015/2/10/8013531/jeb-bush-florida-...
As it turned out, the cache of thousands of emails contained things that are hard to anticipate. Including people emailing their SSN, or talking about their employment/medical issues; the former is possible to filter out computationally, the latter would require manual review and judgment. Bush was criticized, and in response, he took down the emails temporarily until employees could clean them up. But AFAIK, he didn't do anything illegal, because he mirrored exactly what was available from the state official archive which, again AFAIK, did not alter its copy.
This is similar to AOL's release of its search logs. It thought anonymizing user identities would provide anonymity, but they did not realize that some users write very personal things into the search box: https://en.wikipedia.org/wiki/AOL_search_data_leak
1) They don't realise email is not secure
2) When you explain point 1, all of the other solutions seem like too much hassle so they email anyway.
3) You can tell your customers not to email you CC numbers, you can even refuse them, but they will keep sending them
The Payment Card Industry Data Security Standard (PCI DSS) that you have to agree to follow in order to be allowed to process credit cards requires secure storage of all the cards you store--not just the cards that you intended to store or just cards that come in through channels you intended for receiving cards.
This is a serious issue to take into account when choosing your chat system, ticketing system, and email system because you can't just ignore those wayward credit cards. If you choose systems whose developers did not consider this and failed to provide good tools for finding and redacting unrequested, unwanted sensitive information you will end up having to hack such tools into the system yourself.
But then I implemented one on a busy mail system, and I started seeing credit card numbers very regularly. I mean, consistently. Even after people have been told why their emails are being bounced and no, I give an "ETA on when it will be fixed".
You fill out the form, how do you transmit it back to HR? You're probably going to email it. Very few companies have a "secure document transfer system" and very few people understand the risks of emailing personal information.