Sweet.. haven't checked the list in a while.
Take the AC series, for example: https://www.protondb.com/search?q=creed
But once you do that the games actually run, I've gotten Odyssey and Unity to run and they run surprisingly well. If Valve can convince Ubisoft to at least make the launchers not be too intrusive and can solve that last 10% of the config issue then it'd be viable.