Honestly 25 mph isn't that fast. Many healthy cyclists can achieve 25 mph quite easily, although perhaps not for a very long time. If you regularly cycle in places with steeper slopes, 25 mph can be achieved without much effort.
But I think the smallness of the scooters themselves could contribute to a feeling of being unsafe. Psychologically it feels that the object is too small to be able for the user to remain in control. This is in contrast to a bike, when the user simply feels more in control even at a similar speed.