OneSoil suggests 325k hectares of UK land dedicated to potato growing in 2017, over twice as much as the 145k reported by DEFRA; 378k ha of maize cultivation vs 195k according to DEFRA.
Other figures from OpenSoil such as barley and wheat are much closer to the reported figure and so may be fairly accurately categorised by its ML process, and some figures are going to be hard to fairly compare due to different categories or multiple crops per year)
At the same, having had a former colleague work on using Sentinel-2 data to classify land use, I'm well aware it's not an easy problem to solve.