Redis Enterprise is probably the biggest CRDT usage in databases, used to sync geo-replicated active-active clusters: https://redislabs.com/landing/active-active/
There's also Datanet/Kuhiro which was a novel fully distributed database using CRDTs to always merge state across disruptions to a global view, although now seemingly dysfunct: http://highscalability.com/blog/2016/10/17/datanet-a-new-crd...