In this particular case:
- Go is created by google
- Ian Lance Taylor, the author of gccgo, works for Google
- Taylor has worked on gcc for more than a decade
- Google uses gcc for all its infrastructure
I doubt they would object to an LLVM front-end, and I'm sure someone will create one in the future.
As to why Google doesn't use LLVM, the generated code is simply not as fast as GCC. Google (last I heard) employs about 30 compiler engineers to support gcc internally, so they're not about to switch over to a less mature platform, even though it shows great potential.