When the atom is coupled with the electromagnetic field and the state of the system is not separable there is no complete description of the atom given by a wavefunction defining its quantum state. You can have an incomplete description by tracing out the rest of the system, I agree.
Let’s say then that "An atom can be completely described by its quantum state only if it's isolated and in that case its energy is constant."
Edit: in any case, my point was (and I think that we will agree) that it is misleading to say “Consider a system that transitions from energy state 0 to an adjacent energy state 1. [...] To go smoothly from 0 to 1, the system transitions through a series of superpositions of both states”.
The atom goes from the state 0 to the state 1 but during the transition it’s not described by a superposition of those states (that would be a pure state). If anything, it is described by an (improper) mixture of those states, obtained by tracing out the rest of the system.