What kind of sync is that? Only if you manage your vaults externally (e.g. Dropbox)?
It's definitely stored for Touch ID/fingerprint 1password access though (https://support.1password.com/touch-id-security-ios/).
One of their employees wrote about it here: https://discussions.agilebits.com/discussion/106629/ios-secu.... His response is basically that OS-level 0days aren't in their threat model, so they're continuing their usual bug-fixing routine. And it's true, nothing can really stop a rootkit from sniffing passwords as they're being used, besides winning the anti-rootkit race. Perhaps 1password could have a little more explanation of the insecurity of using Touch ID / Face ID though rather than simply saying it's as secure as possible.