Because access (even if they do, which they dont) to startup emails is not enough to replicate startup's success.
Would you write down everything you're doing, and post it to a competitor? Because if you work in an area Google's interested in then that's what you're doing, modulo a privacy policy you'll never find out they've violated (and has happened at least once before - http://articles.latimes.com/2010/sep/16/business/la-fi-googl...).
In this day and age, information travels fast enough that trying to keep a lid on your top talent is probably useless, but still good to have that information under your control.