Without Enterprise, there's just one magic shared key "password" known to every user of the network.
The Enterprise mode outsources authentication of participants to a separate service using EAP and nearly always ends up leveraging TLS to actually make this secure one way or another.
This enables, for example, EduROAM in which academics and students use their "home" institution credentials to get network access in any participating educational network.
The "big boys" probably use custom made silicon (but even then I've seen custom-made silicon with an ESP8266 mounted onto it to abstract out the wifi connection part), but I wouldn't be surprised if the majority of IIoT startups use the ESPs as part of their products.
If the latter, can I make my own real eduroam AP?
Since TLS ends up in the picture many institutions use the Web PKI, so a typical modern device already understands how to verify that this is the right server for example@example.com to authenticate against, it's the one with a Certificate for the DNS name example.com. But yes, they can do all this with custom certificates instead and I'm sure lots do that.
Yes, you can in principle make an EduROAM service. You should probably talk to whatever higher education or further education IT body exists in your country.
Notice that only academics and students get to access the network, so unless you're either of those things you'll need to also add an escape hatch for yourself and anybody else you want using it. Offering the service to others does not entitle you to any access, it would be only a courtesy to others.