I did research for my PhD working towards this. We trapped and laser cooled Th3+ with the intent to isolate and measure this transition optically that way.
https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.10...
I did research for my PhD working towards this. We trapped and laser cooled Th3+ with the intent to isolate and measure this transition optically that way.
https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.10...
But for lasers, I thought the frequency was driven by the energy difference between electron states for a given species? How do you synthesize an arbitrary frequency for a laser without something crazy like a FEL?
You need to narrow their emission wavelength to something ~ the atomic transition (MHz) and then carefully tune it as you say.
Typically diffraction grating is used to carefully feedback some of the laser's output (<10%) back into it, and this can be used to to narrow the emission from several nm to MHz, and to coarsely tune the frequency to few 10-100 Ghz.
Fine tuning is done by changing the current flowing through the laser or the temperature of the junction. These both cause a frequency shift on the MHz scale scale.
You might fine it interesting, you can also use VCOs for fine tuning, but you take the generated RF and send it into a crystal called an Austo-optic modulator. The laser light refracts from the RF phonons propagating through the crystal and this can be used to shift the laser light by the RF frequency.
To expound slightly on your (correct) explanation: The phonons impart (or remove) energy to (from) the laser light, the same way a moving mirror does: via doppler shift.
I made a differential heterodyne interferometer in undergrad using the method you describe.
The intrinsic frequency stability of almost all lasers is by far not good enough to be able to probe such transitions. Therefore, ultra-stable optical cavities are used as a frequency reference, and the laser is constantly steered to stay on the cavity resonance by a fast electronic feedback system. In this way, laser linewidths in the sub-Hz range can be achieved. Then an acousto-optic modulator is used to scan the laser frequency across the clock transition.