That's not how deductions work. A donation costs the donor much more than the tax reduction. All a deduction does is reduce your adjusted gross income, not literally offset the nominal sum you pay in taxes.
Say my top marginal tax bracket is 20%. If I donate $100 then it's costing me precisely $100. If I don't donate then I'm on the hook for $20 ($100 * 20%) in tax. $100 > $20. This presumes the $100 is earned income, and that the donation is in fact tax deductible. If neither of those hold then the relation is $100 > $0.
People have similarly mistaken ideas about so-called write-offs: https://www.youtube.com/watch?v=XEL65gywwHQ