Putting complex business logic in the database is opening up all sorts of interesting new ways for data to be unavailable, corrupted or complicated to access. It is easy to imagine it working out well for simple requirements where there just needs to be something that works.
PostgreSQL is a piece of software that takes data and enforces the relational data model on it. Great idea. But the relational model of data is really only tuned to relational algebra. Put complex logic in there and all that is really being accomplished is now you can't migrate away from PostgreSQL. Relational databases already have great integration with every other programming language in current use.